Benzoic Acid → HCID 53873217, compound

Participants

Reaction Steps

In analogous manner as described in Example 24, but using the starting compounds of formula III indicated in the following Table, the following compounds of general formula I are obtained:Ex. Empirical Molecu- Analysis % Starting com- formula lar nD20 Calc. pound of for- weight Found mula III C H Br Cl N S__________________________________________________________________________25 2-(5-Isopropoxy-3- methyl-2-pentenylthio)- C17H24O3S 308.4 1.5492 66.2 7.8 -- -- -- 10.4 2-Mercapto- benzoicacid-methylester 66.9 7.9 -- -- -- 10.4 benzoic- acid methylester26 3-(5-Isopropoxy-3-methyl- C15H21BrO2 313.2 1.5138 57.5 6.8 25.5 -- -- -- 3-Bromo- 2-pentenyloxy)-bromobenzol 58.1 7.0 25.1 -- -- -- phenol27 4-(5-Isopropoxy-3-methyl- C15H21ClOS 284.8 1.5332 63.3 7.4 -- 12.4 -- 11.3 4-Chloro- 2-pentenylthio)-chlorobenzol 63.1 7.6 -- 13.0 -- 10.6 phenol28 4-(5-Isopropoxy-3-methyl- C16H24O3 264.4 1.5050 72.7 9.2 -- -- -- -- 4-Methoxy- 2-pentenyloxy)-anisole 72.3 9.5 -- -- -- -- phenol29 4-(5-Isopropoxy-3-methyl- C16H24O2S 280.4 1.5329 68.5 8.6 -- -- -- 11.4 4-(Methyl- 2-pentenyloxy)-thioanisole 68.0 8.6 -- -- -- 10.9 thio)-phenol30 4-(5-Isopropoxy-3-methyl-2- C17H26O2 262.4 1.4992 77.8 10.0 -- -- -- -- 4-entyl- pentenyloxy)-ethylbenzol 77.5 10.7 -- -- -- -- phenol31 4-(5-Isopropoxy-3-methyl-2- C15H21NO4 279.3 1.5335 64.5 7.6 -- -- 5.0 -- 4-Nitro- pentenyloxy)-nitrobenzol 64.4 7.7 -- -- 4.8 -- phenol32 4-(5-Isopropoxy-3-methyl-2- 59.4 6.6 -- 23.4 -- -- 2,4-Dichloro- pentenyloxy)-1,3-dichloro- C15H20Cl2O2 303.2 1.5244 59.4 6.6 -- 23.6 -- -- phenol benzol__________________________________________________________________________

Provenance & Evidence