Sodium Carbonate → HCID 54348461, compound

HRID 1580748Notes

Reaction equation

HRID 1580748 reaction equation
Cl[CH2:2][CH:3]=[CH:4][CH2:5][CH2:6][O:7][CH:8]([CH3:10])[CH3:9].C(=O)([O-])[O-:12].[Na+].[Na+]>O>[CH:8]([O:7][CH2:6][CH2:5][CH:4]=[CH:3][CH2:2][OH:12])([CH3:10])[CH3:9]

Participants

4

Reactant 2

HCID 10340Sodium CarbonateHCID 54043382HCID 54043382, compound

Product 1

HCID 54348461HCID 54348461, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

8.13 g (0.05 mol) of 1-chloro-5-isopropoxy-2-pentene are added to a solution of 6.5 g of sodium carbonate in 60 cc of water and the mixture is heated to 95°-98° during 18 hours. After cooling the organic parts are extracted with benzene, the benzene extract is washed with saturated salt solution and dried with sodium sulphate. The solvent is distilled off and then it is distilled at reduced pressure. According to gas-chromatography pure 5-isopropoxy-2-penten-1-ol distils at 102°-104°/15 mm. nD20 = 1.4363.

Workup

  1. temperaturethe mixture is heated to 95°-98° during 18 hours
  2. temperatureAfter cooling the organic parts
  3. extractionare extracted with benzene
  4. extractionthe benzene extract
  5. washis washed with saturated salt solution
  6. dry with materialdried with sodium sulphate
  7. distillationThe solvent is distilled off
  8. distillationit is distilled at reduced pressure
  9. customdistils at 102°-104°/15 mm

Sources & evidence

ORD record
ord-41d26020a25d44b59472d35e5f10de2a
Source dataset
uspto-grants-1976_01
Patent number
US03933804

Reaction notes

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