Methyl Ethyl Ketone → 2-[(1-Methylpropyl)]-9-[(1-hydroxy-1-methylpropyl)]-1,10-phenanthroline

HRID 1581761Notes

Reaction equation

HRID 1581761 reaction equation
[I-].[I-].[Sm+2].[CH3:4][CH:5]([C:8]1[CH:21]=[CH:20][C:19]2[C:10](=[C:11]3[C:16](=[CH:17][CH:18]=2)[CH:15]=[CH:14][CH:13]=[N:12]3)[N:9]=1)[CH2:6][CH3:7].[CH3:22][C:23](=[O:26])[CH2:24][CH3:25]>>[CH3:4][CH:5]([C:8]1[CH:21]=[CH:20][C:19]2[C:10](=[C:11]3[C:16](=[CH:17][CH:18]=2)[CH:15]=[CH:14][C:13]([C:23]([OH:26])([CH3:22])[CH2:24][CH3:25])=[N:12]3)[N:9]=1)[CH2:6][CH3:7]

Participants

4

Reactant 3

HCID 6569Methyl Ethyl KetoneHCID 129940742-sec-Butyl-1,10-phenanthrolineHCID 178506586HCID 178506586, compound

Product 1

HCID 227234122-[(1-Methylpropyl)]-9-[(1-hydroxy-1-methylpropyl)]-1,10-phenanthroline

Procedure

The title compound is prepared by following the General Procedure I with samarium diiodide and 2-(2-butyl)-1,10-phenanthroline, prepared as described by Example 16, and 2-butanone.

Workup

  1. customprepared

Sources & evidence

ORD record
ord-24147d16c7c24fdaa3f02b4d59d1a949
Source dataset
uspto-grants-2004_05
Patent number
US06730788B1

Reaction notes

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