Furan → 2,5-Dimethoxytetrahydrofuran

HRID 1581893Notes

Reaction equation

HRID 1581893 reaction equation
O1C=CC=C1.[CH3:6][O:7][CH:8]1[CH2:12][CH:11]=[C:10]([O:13][CH3:14])[O:9]1>>[CH3:6][O:7][CH:8]1[CH2:12][CH2:11][CH:10]([O:13][CH3:14])[O:9]1

Participants

3

Reactant 2

HCID 8029Furan2×HCID 23505276HCID 23505276, compound

Product 1

HCID 790982,5-DimethoxytetrahydrofuranYield 3.3%

Procedure

After 1 F/mol of furan, the GC-percentage by area of furan had been reduced from 22.7 to 16.9%, and the GC-percentage by area of 2,5-dimethoxydihydrofuran remained at 30%. At the same time, 3.3% of 2,5-dimethoxytetrahydrofuran were formed.

Sources & evidence

ORD record
ord-285be2aec6ff4ebdb643e667f1817081
Source dataset
uspto-grants-2004_05
Patent number
US06733652B1

Reaction notes

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