Hexadiene → HCID 22717334, compound

Participants

Reaction Conditions

Reaction Steps

As in Example 1, 1,3-hexadiene (1.00 g, 12.17 mmol), trichlorosilane (6.59 g, 48.65 mmol) and tetrabutylphosphonium chloride (0.36 g, 1.22 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 8 hours. The resulting mixture was distilled to yield 1.64 g (yield: 74%) of 1,1-dichloro-2,5-dimethylsilacyclo-3-pentene and 0.43 g (yield: 10%) of 2,5-bis(trichlorosilyl)-3-hexene main products.

Provenance & Evidence