1,3-Cyclohexadiene → HCID 22717324, compound

Participants

Reaction Conditions

Reaction Steps

As in Example 1, 1,3-cyclohexadiene (0.98 g, 12.23 mmol), trichlorosilane (6.63 g, 48.95 mmol) and tetrabutylphosphonium chloride (0.35 g, 1.19 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 12 hours. The resulting mixture was distilled to yield 1.92 g (yield: 45%) of 2,6-bis(trichlorosilyl)-1-hexene.

Provenance & Evidence