1,3-Cycloheptadiene → HCID 22717325, compound

Participants

Reaction Conditions

Reaction Steps

As in Example 1, 1,3-cycloheptadiene (1.00 g, 10.62 mmol), trichlorosilane (5.76 g, 42.52 mmol) and tetrabutylphosphonium chloride (0.31 g, 1.05 mmol) were added in a 25 mL stainless steel tube under nitrogen atmosphere. After sealing the cylinder with a cap, the reactor was maintained at 180° C. for 18 hours. The resulting mixture was distilled to yield 0.96 g (yield: 25%) of 2,6-bis(trichlorosilyl)-1-heptene.

Provenance & Evidence