HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Methoxide → HCID 53906052, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Reactant | HCID 53825677 | HCID 53825677 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 53906052 | HCID 53906052 | — |
Reaction Steps
A solution of 4 (500 mg) in dry methanol (10 ml) is deacetylated with sodium methoxide (25 mg), and worked up in the normal manner to give a crystalline mass. Recrystallization from isopropanol affords 5 in near quantitative yield (323 mg); m.p. 145°-146° C.; [α]D27 -215±1.0° (C 0.97, methanol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04554349 |
| Source dataset | uspto-grants-1985_11 |
| ORD ID | ord-a4b5191c0aeb43878e0a488bc0ad4bd1 |
| Source note | uspto-grants-1985_11 |