HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Methoxide → HCID 53690551, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Methoxide | HCID 10942334 | — |
| Reactant | HCID 54358027 | HCID 54358027 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 53690551 | HCID 53690551 | 78.1% |
Reaction Steps
A solution of 12 (4.4 g) in dry methanol (60 ml) is deacetylated with sodium methoxide (0.5 g). The product is isolated in the normal manner and purified by column chromatography (CHCl3 --MeOH--H2O, 95:5:5, v/v) to give 13 as an oil (2.5 g, 78%): [α]D27 +220±0.9° (C 1.06 methanol).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04554349 |
| Source dataset | uspto-grants-1985_11 |
| ORD ID | ord-74e59d71e72c48c2a10b75ee1f81c62c |
| Source note | uspto-grants-1985_11 |