L-Phenylalanine, methyl ester → N-acetoacetyl-L-aspartyl-L-phenylalanine methyl ester

HRID 1583892Notes

Reaction equation

HRID 1583892 reaction equation
[C:1]([NH:7][C@@H:8]1[C:13](=[O:14])[O:12][C:10](=[O:11])[CH2:9]1)(=[O:6])[CH2:2][C:3]([CH3:5])=[O:4].[CH3:15][O:16][C:17](=[O:27])[C@H:18]([CH2:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[NH2:19]>>[CH3:15][O:16][C:17](=[O:27])[C@H:18]([CH2:20][C:21]1[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1)[NH:19][C:13](=[O:14])[C@H:8]([CH2:9][C:10](=[O:11])[OH:12])[NH:7][C:1](=[O:6])[CH2:2][C:3]([CH3:5])=[O:4]

Participants

3

Reactant 2

HCID 736234L-Phenylalanine, methyl esterHCID 13334674N-acetoacetyl-L-aspartic anhydride

Product 1

HCID 13334676N-acetoacetyl-L-aspartyl-L-phenylalanine methyl ester

Procedure

reacting N-acetoacetyl-L-aspartic anhydride with L-phenylalanine methyl ester to form N-acetoacetyl-α-L-aspartyl-L-phenylalanine methyl ester.

Sources & evidence

ORD record
ord-49e83bc0599c4876a72b885b5508bea5
Source dataset
uspto-grants-1985_11
Patent number
US04555362

Reaction notes

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