Ammonia → HCID 88668119, compound

HRID 1583924Notes

Reaction equation

HRID 1583924 reaction equation
[NH2-].[NH2-].[Ca+2:3].[CH2:4]([CH:6]([CH2:9][CH2:10][CH2:11][CH3:12])[CH2:7][OH:8])[CH3:5].N>C1CCCCC1>[CH2:4]([CH:6]([CH2:9][CH2:10][CH2:11][CH3:12])[CH2:7][O:8][CH2:7][CH:6]([CH2:4][CH3:5])[CH2:9][CH2:10][CH2:11][CH3:12])[CH3:5].[Ca:3]

Participants

5

Reactant 3

HCID 222AmmoniaHCID 77202-EthylhexanolHCID 134991127HCID 134991127, compound

Product 1

HCID 88668119HCID 88668119, compound

Reagents, catalysts & solvents 1

HCID 8078CyclohexaneSolvent

Procedure

To 7.2 g (0.1 mole) of calcium amide slurried in 100 ml of cyclohexane, there is added 23.5 g (28.2 ml, 0.18 moles) of 2-ethyl-1-hexanol gradually over a 10-15 minute period. Ammonia is given off throughout the addition. The mixture is heated to reflux for several hours to remove entrained ammonia, and is then cooled and filtered. The resultant clear, light amber solution is 0.8M in Ca.

Workup

  1. temperatureThe mixture is heated
  2. temperatureto reflux for several hours
  3. customto remove
  4. temperatureis then cooled
  5. filtrationfiltered

Sources & evidence

ORD record
ord-470f52af8e3e40f79dd8de942fdc08b1
Source dataset
uspto-grants-1985_11
Patent number
US04555498

Reaction notes

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