HCID 20034742, compound → HCID 131721331, compound

HRID 1584699Notes

Reaction equation

HRID 1584699 reaction equation
[CH:1]([O-:3])=[O:2].[CH:4]([O-:6])=[O:5].[K+].[K+].[CH:9]([O-:11])=[O:10].[CH:12]([O-:14])=[O:13].[Na+:15].[Na+]>>[CH:1]([O-:3])=[O:2].[CH:4]([O-:6])=[O:5].[CH:9]([O-:11])=[O:10].[CH:12]([O-:14])=[O:13].[Na+:15].[Na+:15].[Na+:15].[Na+:15]

Participants

3

Reactant 2

HCID 20034742HCID 20034742, compoundHCID 129669943HCID 129669943, compound

Product 1

HCID 131721331HCID 131721331, compound

Procedure

Potassium diformate is a most stable crystalline salt having a decomposition temperature above 120° C. while ammonium diformates are less stable and decompose in the range 20-25° C. Sodium diformate is reported to decompose in the range 100-120° C. Sodium tetra-formate can also be formed according to a similar reaction mechanism. When these salts decompose, acid is released.

Workup

  1. customin the range 20-25° C
  2. customto decompose in the range 100-120° C

Sources & evidence

ORD record
ord-563e8c4ae3f04757855a66a405752fc0
Source dataset
uspto-grants-1999_08
Patent number
US05935625

Reaction notes

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