Bromide ion → HCID 14974059, compound

HRID 1585467Notes

Reaction equation

HRID 1585467 reaction equation
C[O:2][C:3]([CH3:15])([CH3:14])[C:4]([CH3:13])([CH3:12])[CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.CC(C)(CC1C=CC=CC=1)C(=O)C.[Br-].[I-]>>[CH3:15][C:3]([OH:2])([C:4]([CH3:13])([CH3:12])[CH2:5][C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[CH3:14]

Participants

5

Reactant 4

HCID 259Bromide ionHCID 30165Iodide IonHCID 836703,3-Dimethyl-4-phenylbutan-2-oneHCID 21218520(3-Methoxy-2,2,3-trimethylbutyl)benzene

Product 1

HCID 14974059HCID 14974059, compound

Procedure

Finally, 3-methoxy-2,2,3-trimethyl-1-phenylbutane (see line (3) of the scheme below) is prepared from 3,3-dimethyl-4-phenyl-2-butanone which is reacted with a methyl magnesium halide, e.g. the bromide or iodide, to obtain 2,3,3-trimethyl-4-phenyl-2-butanol. As in the synthesis described above for the other compounds of the invention, this alcohol is then etherified to obtain the desired product. ##STR1##

Sources & evidence

ORD record
ord-11996ac8bc644d599e751c6b10e1b443
Source dataset
uspto-grants-1999_08
Patent number
US05939368

Reaction notes

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