HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous Chloride → 3,4-Diamino-5-nitrobenzonitrile
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous Chloride | HCID 24479 | — |
| Reactant | 4-Amino-3,5-dinitrobenzonitrile | HCID 21217844 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 3,4-Diamino-5-nitrobenzonitrile | HCID 21217846 | 42.4% |
Reaction Steps
To 4-amino-3,5-dinitrobenzonitrile (9.4 g, 0.045 mol) in EtOH (100 mL) was added SnCl2 (30 g, 0.16 mol). The mixture was refluxed for 1 h. The reaction was then filtered and the filtrate concentrated to afford 3,4-diamino-5-nitrobenzonitrile (3.4 g, 42%) of an orange solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05942532 |
| Source dataset | uspto-grants-1999_08 |
| ORD ID | ord-af5fc443f350485a82517404f2651223 |
| Source note | uspto-grants-1999_08 |