HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetonitrile → HCID 67860126, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetonitrile | HCID 6342 | — |
| Reactant | Trifluoroacetic acid | HCID 6422 | — |
| Reactant | Ninhydrin | HCID 10236 | — |
| Reactant | Potassium Permanganate | HCID 516875 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 67860126 | HCID 67860126 | — |
Reaction Steps
To 1.54 gm (4 mmole) of T-Boc-D-Phe-L-Pro-Me (3) 35 ml of trifluoracetic acid was added. This solution was stirred at 0° C. (H2O/ice) for one hr. as the bath gradually rose to room temperature. TLC acetonitrile:water:acetic acid (EtOAc:Hex, 4:6) using the KMnO4 stain showed complete disappearance of starting material. TLC (CH3CN:H2O:AcOH, 94:5:1, ninhydrin stain) indicated one product (Rf 0.7).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05217705 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-985a7059972f45fbb6c7e8045d47564c |
| Source note | uspto-grants-1993_06 |