HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 4-(tert-Butyldimethylsilanyloxymethyl)pyridine 1-oxide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 4-(Tert-butyldimethylsilyloxymethyl)pyridine | HCID 10987880 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 4-(tert-Butyldimethylsilanyloxymethyl)pyridine 1-oxide | HCID 21781515 | — |
Reaction Steps
A solution of 40.6 g of 4-(tert-butyl-dimethylsilyloxymethyl)-pyridine and 40 g of m-chloroperbenzoic acid in 500 ml methylene chloride is stirred 16 hours at room temperature. Solution is washed with 2N sodium hydroxide and water, dried over sodium sulfate, filtered and concentrated in vacuo to yield 4-(tert-butyldimethylsilyloxymethyl)-pyridine-N-oxide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05217963 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-a1856e06f9224a3e8af4b55038bc8e20 |
| Source note | uspto-grants-1993_06 |