HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 54012127, compound → HCID 14541450, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 54012127 | HCID 54012127 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | HCID 14541450 | HCID 14541450 | — |
Reaction Steps
A solution of 7.9 g of ethyl 1-(tert-butoxycarbonyl)-4-(hydroxymethyl)-piperidine-2-carboxylate and 9.9 g of pyridinium chlorochromate in 175 ml of methylene chloride is stirred at room temperature for 3 hours. The mixture is filtered and purified by flash chromatography using ethyl acetate/hexane (25:75) to yield 1-(tert-butoxycarbonyl)-2-ethoxycarbonylpiperidine-4-carboxaldehyde.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05217963 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-14a3f65d84bf4a658079a5b59d3b66f4 |
| Source note | uspto-grants-1993_06 |