HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Acetoxy-4'-methoxy-1,1'-biphenyl → 4-Methylcarbonyloxy-4'-hydroxybiphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Acetoxy-4'-methoxy-1,1'-biphenyl | HCID 18956602 | — |
| Reactant | alpha-Methyl-4'-(methoxy)[1,1'-biphenyl]-4-acetic acid, ethyl ester | HCID 86746941 | — |
| Product | 4-Methylcarbonyloxy-4'-hydroxybiphenyl | HCID 14438409 | — |
Reaction Steps
The title compound is prepared using the method of part B of Example 16 substituting 4-acetoxy-4'-methoxy-1,1'-biphenyl for α-methyl-4'-(methoxy)[1,1'-biphenyl]-4-acetic acid, ethyl ester. Normal workup affords a white solid, m.p. 204°-207° C.; MS (EI m/z): 212 (M)+, 197 (b.p.,M--CH3)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05218124 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-b7ef6823efd1404cb499be1fa1e9cdd5 |
| Source note | uspto-grants-1993_06 |