HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3-Dimethyl-2-imidazolidinone → 1-(2-Cyanophenyliminomethyl)-2-nitroiminoimidazolidine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3-Dimethyl-2-imidazolidinone | HCID 6661 | — |
| Reactant | 2-Aminobenzonitrile | HCID 72913 | — |
| Reactant | 1-Diethoxymethyl-2-nitroiminoimidazolidine | HCID 136403419 | — |
| Catalyst | Tin tetrachloride | HCID 24287 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | 1-(2-Cyanophenyliminomethyl)-2-nitroiminoimidazolidine | HCID 136331487 | 130.4% |
Reaction Steps
0.05 g of SnCl4 was added to a mixture of 2.0 g of 1-diethoxymethyl-2-nitroiminoimidazolidine, 1.02 g of o-aminobenzonitrile and 5 ml of 1,3-dimethyl-2-imidazolidinone, followed by agitation at room temperature for 10 minutes. Ether was added to the reaction mixture, and the resultant crystals were collected by filtration and dried to give 2.9 g of 1-(2-cyanophenyliminomethyl)-2-nitroimino-imidazolidine.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05219868 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-ce4c7014e8c44b01932389f6a4a7a856 |
| Source note | uspto-grants-1993_06 |