HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dibromomethane → HCID 19756491, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dibromomethane | HCID 3024 | — |
| Reactant | Dichloromethane | HCID 6344 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | HCID 19756489 | HCID 19756489 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Product | HCID 19756491 | HCID 19756491 | — |
Reaction Steps
To a solution of 5 g (0.021 mol) 2-[4-(phenylethinyl)phenyl]-butyronitrile in 65 ml CH2Br2 are added, with stirring, 64 g 50% (0.8 mol) NaOH and 5.5 g (0.025 mol) benzyltriethylammoniumchloride. The mixture is stirred for 5 hours at 95°, cooled and 250 ml CH2Cl2 are added. The organic phase is separated off, washed, dried and evaporated in vacuum. The thus obtained title compound is kept for one hour at 70°-80° under high vacuum and crystallises from toluene: ligroine 1:2, m.p. 107°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05219876 |
| Source dataset | uspto-grants-1993_06 |
| ORD ID | ord-46c63b5b3c5642ffbccc1a59f92e9110 |
| Source note | uspto-grants-1993_06 |