Diisobutylaluminumhydride → HCID 12200649, compound

HRID 1587994Notes

Reaction equation

HRID 1587994 reaction equation
[CH3:1][O:2][CH:3]([O:10][CH3:11])[CH2:4][C@H:5]1[O:7][C@@H:6]1[CH2:8][OH:9].O(O)O.[H-].C([Al+]CC(C)C)C(C)C>C1C=CC=CC=1>[CH3:11][O:10][CH:3]([O:2][CH3:1])[CH2:4][CH2:5][CH:6]([OH:7])[CH2:8][OH:9]

Participants

4

Reactant 2

HCID 21225700DiisobutylaluminumhydrideHCID 86746974HCID 86746974, compound

Product 1

HCID 12200649HCID 12200649, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The epoxy alcohol (2R,3R) 3-(2,2-dimethoxyethyl)oxiranemethanol is reacted with diisobutylaluminum hydride, in benzene, to obtain 5,5-dimethoxypentane-1,2-diol: ##STR11##

Sources & evidence

ORD record
ord-d97f32d4407a44f781c809c19279caf8
Source dataset
uspto-grants-1993_06
Patent number
US05220003

Reaction notes

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