Thiophenol → HCID 131717982, compound

HRID 1587995Notes

Reaction equation

HRID 1587995 reaction equation
[CH3:1][O:2][CH:3]([O:10][CH3:11])[CH2:4][C@H:5]1[O:7][C@@H:6]1[CH2:8][OH:9].O(O)O.[C:15]1([SH:21])[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[S:21]([CH:5]([CH2:4][CH:3]([O:10][CH3:11])[O:2][CH3:1])[CH:6]([OH:7])[CH2:8][OH:9])[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1

Participants

3

Reactant 2

HCID 7969ThiophenolHCID 86746974HCID 86746974, compound

Product 1

HCID 131717982HCID 131717982, compound

Procedure

The epoxy alcohol (2R,3R) 3-(2,2-dimethoxyethyl)oxiranemethanol is reacted with thiophenol in the presence of a metal catalyst to obtain 3-thiophenoxy-5,5-dimethoxy pentane-1,2-diol: ##STR15##

Sources & evidence

ORD record
ord-69dbcc76c4314769b83d9d700b7aa36d
Source dataset
uspto-grants-1993_06
Patent number
US05220003

Reaction notes

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