HCID 19754682, compound → 2-(Cyclopentylidenemethyl)benzenamine
Reaction equation
[C:1]1(=[CH:6][C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=2[N+:13]([O-])=O)[CH2:5][CH2:4][CH2:3][CH2:2]1.C1(CC2C=CC=CC=2[N+]([O-])=O)CCCC=1.C1(CC2C=CC=CC=2N)CCCC=1>>[C:1]1(=[CH:6][C:7]2[CH:12]=[CH:11][CH:10]=[CH:9][C:8]=2[NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5]1Participants
4
Procedure
In the preparation of 1-(cyclopentylidenemethyl)-2-nitrobenzene, its isomer, 1-[(cyclopent-1-enyl)methyl]-2-nitrobenzene, was also isolated and then converted to 2-[(cyclopent-1-enyl)methyl]aniline.
Workup
- customwas also isolated
Sources & evidence
- ORD record
- ord-b25e228b93dc4a13a2768535499b45f4
- Source dataset
- uspto-grants-1993_06
- Patent number
- US05223526
Reaction notes
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