103108-04-9 → HCID 19754836, compound

HRID 1588884Notes

Reaction equation

HRID 1588884 reaction equation
[CH:1]1([CH:4]([C:8]2[CH:13]=[CH:12][C:11]([C:14]([F:17])([F:16])[F:15])=[CH:10][CH:9]=2)[CH2:5][CH2:6][OH:7])[CH2:3][CH2:2]1.[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1.FC(F)(F)C1C=CC(C(C)C=O)=CC=1>C(Cl)Cl>[CH:1]1([CH:4]([C:8]2[CH:9]=[CH:10][C:11]([C:14]([F:15])([F:16])[F:17])=[CH:12][CH:13]=2)[CH2:5][CH:6]=[O:7])[CH2:3][CH2:2]1

Participants

5

Reactant 3

HCID 13510285103108-04-9HCID 19754851HCID 19754851, compoundHCID 178418287HCID 178418287, compound

Product 1

HCID 19754836HCID 19754836, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

This compound was prepared in a manner analogous to that of Example 1, Step D, using 2.5 grams (0.01 mole) of 3-cyclopropyl-3-(4-trifluoromethylphenyl)propan-1-ol and 8.6 grams (0.04 mole) of pyridinium chlorochromate in 50 ml of methylene chloride. The yield of 3-cyclopropyl-3-pressure (4-trifluoromethylphenyl)propionaldehyde was 1.4 grams.

Workup

  1. customThis compound was prepared in a manner analogous to that of Example 1, Step D

Sources & evidence

ORD record
ord-80abe711ef4f49f08d8bdd05f65ba5c0
Source dataset
uspto-grants-1993_06
Patent number
US05223536

Reaction notes

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