HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Phenol → 2,4,6-Tris(2-methylbutan-2-yl)phenol
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Phenol | HCID 996 | — |
| Edukt | 4-tert-Pentylphenol | HCID 6643 | — |
| Edukt | 2,4-Di-tert-pentylphenol | HCID 8455 | — |
| Edukt | 2-tert-Amylphenol | HCID 76769 | — |
| Produkt | 2,4,6-Tris(2-methylbutan-2-yl)phenol | HCID 15173855 | 10,8% |
Reaktionsschritte
The procedure of Example 1 was repeated except that 1.00 g (10.6 millimoles) of phenol, 11.4 g of the same C5 fraction as used in Example 1, and 1.00 g of Silica-Alumina "IS-28" (produced by Shokubai Kasei Kogyo Co., Ltd.) which had been burned at 500° C. for 10 hours were used. The acid strength of the silica alumina (as determined in the same manner as in Example 1) was as follows: H0 ≤- 8.2. The proportion of the unreacted phenol was 5.0%, and 0.05 g (2.9%) of o-tert-amylphenol, 0.22 g (12.6%) of p-tertamylphenol, 1.73 g (69.6%) of 2,4-di-tert-amylphenol, and 0.01 g (0.3%) of 2,4,6-tri-tert-amylphenol were formed.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04568778 |
| Quelldatensatz | uspto-grants-1986_02 |
| ORD ID | ord-e60bef2d4ba84997af8d0ec51740afcf |
| Quellennotiz | uspto-grants-1986_02 |