HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Octene → Silane, methyltrioctyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Octene | HCID 8125 | — |
| Reactant | HCID 101074706 | HCID 101074706 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Product | Silane, methyltrioctyl- | HCID 165132 | 86% |
Reaction Steps
A mixture of 61 grams of methyloctylsilane and 186 grams of 1-octene was reacted in the presence of 0.0075 gram of chlorotris(triphenylphosphine)rhodium(I) for 2.5 hours at 85°-89° C. Analysis by GLC showed a total of 15 percent of unsaturated product. After removing unreacted octene by stripping, the residue was hydrogenated as in Example 1. Distillation revealed an 86 percent yield of methyltri(octyl)silane having a boiling point of 188°-189° C. (0.9 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04572791 |
| Source dataset | uspto-grants-1986_02 |
| ORD ID | ord-db7f9e721c0340ab907dd1c1a2552931 |
| Source note | uspto-grants-1986_02 |