HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Decene → Silane, tris(decyl)methyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Decene | HCID 13381 | — |
| Reactant | HCID 123920282 | HCID 123920282 | — |
| Catalyst | Chlorotris(triphenylphosphine)rhodium(I) | HCID 84599 | — |
| Product | Silane, tris(decyl)methyl- | HCID 167744 | 80% |
Reaction Steps
A mixture of 75 grams of methyldecylsilane and 202 grams 1-decene was reacted in the presence of 0.0040 grams of chlorotris(triphenylphosphine)rhodium(I) at 87°-95° C. for one hour. The unreacted decene was stripped off under high vacuum and the residue hydrogenated as above. Distillation gave an 80 percent yield of methyltri(decyl)silane having a boiling point of 230°-233° C. (0.95 mm).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04572791 |
| Source dataset | uspto-grants-1986_02 |
| ORD ID | ord-7146e8eda8a8439a82914675a40078ac |
| Source note | uspto-grants-1986_02 |