HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Decene → Methyltridecylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Decene | HCID 13381 | — |
| Reactant | Methyldidecylsilane | HCID 71366123 | — |
| Catalyst | Carbonylhydridotris(triphenylphosphine)rhodium(I) | HCID 10941995 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | Methyltridecylsilane | HCID 123907608 | 85% |
Reaction Steps
A mixture of 1.53 grams of methyldidecylsilane, and 0.70 gram of 1-decene in 5 milliliters of benzene was reacted for 25 hours at 50° C. in the presence of 0.005 gram hydridocarbonyltris(triphenylphosphine)rhodium(I). Chromatographic analysis showed that an 85 percent yield of methyltridecylsilane was formed at a 65 percent silane conversion.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04572791 |
| Source dataset | uspto-grants-1986_02 |
| ORD ID | ord-41f29fe13006406dbcfb4c156e765557 |
| Source note | uspto-grants-1986_02 |