HCID 178444295, compound → HCID 178461183, compound

HRID 1589758Notes

Reaction equation

HRID 1589758 reaction equation
[F:1][C:2]1[CH:3]=[C:4]([C:9]2[N:14]=[CH:13][C:12]([C:15]3[CH:20]=[CH:19][C:18]([C@H:21]4[CH2:26][CH2:25][C@H:24]([CH2:27]C)[CH2:23][CH2:22]4)=[CH:17][CH:16]=3)=[CH:11][N:10]=2)[CH:5]=[CH:6][C:7]=1[F:8].FC1C=C(C2N=CC(C3C=CC([C@H]4CC[C@H](CCCCC)CC4)=CC=3)=CN=2)C=CC=1F>>[F:1][C:2]1[CH:3]=[C:4]([C:9]2[N:10]=[CH:11][C:12]([C:15]3[CH:20]=[CH:19][C:18]([C@H:21]4[CH2:26][CH2:25][C@H:24]([CH3:27])[CH2:23][CH2:22]4)=[CH:17][CH:16]=3)=[CH:13][N:14]=2)[CH:5]=[CH:6][C:7]=1[F:8]

Participants

3

Reactant 2

HCID 178444295HCID 178444295, compoundHCID 178455710HCID 178455710, compound

Product 1

HCID 178461183HCID 178461183, compound

Procedure

2-(3',4'-difluorophenyl)-5-[4'-(trans-4"-ethylcyclohexyl)phenyl] pyrimidine ##STR45## 2-(3',4'-difluorophenyl)-5-[4'-(trans-4"-butylcyclohexyl)phenyl] pyrimidine ##STR46## wherein S1 and S2 are the smectic phase. 2-(3',4'-difluorophenyl)-5-[4'-(trans-4"-pentylcyclohexyl)phenyl] pyrimidine ##STR47## 2-(3',4,-difluorophenyl)-5-[4'-(trans-4"-hexylcyclohexyl)phenyl] pyrimidine

Sources & evidence

ORD record
ord-d988f987cf5341239b01b5fc39f25a27
Source dataset
uspto-grants-1993_04
Patent number
US05200110

Reaction notes

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