Cyclopentadiene → HCID 14959427, compound

HRID 1589904Notes

Reaction equation

HRID 1589904 reaction equation
[CH:1]1[CH2:5][CH:4]=[CH:3][CH:2]=1.[CH3:6][S:7]([C:10]#[N:11])(=[O:9])=[O:8]>ClCCl>[CH3:6][S:7]([C:10]1[CH:5]2[CH2:1][CH:2]([CH:3]=[CH:4]2)[N:11]=1)(=[O:9])=[O:8]

Participants

4

Reactant 2

HCID 7612CyclopentadieneHCID 90422Methanesulphonyl cyanide

Product 1

HCID 14959427HCID 14959427, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

7.93 g of cyclopentadiene (120 mmol) was added to a solution of 10.51 g of methanesulfonyl cyanide (100 mmol) in 30 ml of dichloromethane within 5 minutes at -20° C. The colorless solution was stirred for another 2 hours at room temperature and then the solvent was distilled off, and the Diels-Alder adduct remains as yellowish solid. Properties of the compound were:

Workup

  1. distillationthe solvent was distilled off

Sources & evidence

ORD record
ord-8f3c155b8c7346d4a6acb0664bb56ab0
Source dataset
uspto-grants-1993_04
Patent number
US05200527

Reaction notes

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