Bromine → 2-Phenyl-6-nitrobenzyl bromide

HRID 1589935Notes

Reaction equation

HRID 1589935 reaction equation
[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[C:9]([N+:13]([O-:15])=[O:14])[C:8]=2[CH3:16])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:17]Br>C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[C:9]([N+:13]([O-:15])=[O:14])[C:8]=2[CH2:16][Br:17])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 24408BromineHCID 105846962-Methyl-3-nitro-1,1'-biphenyl

Product 1

HCID 143174162-Phenyl-6-nitrobenzyl bromideYield 77%

Reagents, catalysts & solvents 1

HCID 7187Benzoyl PeroxideCatalyst

Procedure

The procedure of Example 8 was employed, except that the starting material was 2 g of 2-phenyl-6-nitrotoluene which was reacted with 1.5 g of bromine and 0.110 g of benzoyl peroxide. In this way, 2 g (77% yield) of yellowish crystals were recovered.

Sources & evidence

ORD record
ord-12d1792f5354429e8ed21fb7c34db631
Source dataset
uspto-grants-1993_04
Patent number
US05200544

Reaction notes

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