HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl 3-phenylprop-2-enoate → 3-Phenylprop-2-En-1-Ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl 3-phenylprop-2-enoate | HCID 7649 | — |
| Reactant | Diisobutylaluminumhydride | HCID 21225700 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Solvent | Hexane | HCID 8058 | — |
| Product | 3-Phenylprop-2-En-1-Ol | HCID 308 | 104.5% |
Reaction Steps
The above ester (3.52 g) was treated with diisobutylaluminium hydride (40 ml of a 1M solution in hexane) in dichloromethane (40 ml) in the normal fashion to provide 3-phenylprop-2-en-1-ol (2.8 g). NMR 1H: 7.2(5H,m), 6.55(1H,d), 6.35 (1H,t), 4.25(2H,d), 1.97(1H,s).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05202356 |
| Source dataset | uspto-grants-1993_04 |
| ORD ID | ord-9d68c49d44e541e5a5c4884fa6c373b2 |
| Source note | uspto-grants-1993_04 |