HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethyl Sulfoxide → HCID 18651193, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethyl Sulfoxide | HCID 679 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | (2,6-Dichloropyridin-4-yl)methanol | HCID 2794840 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | HCID 18651193 | HCID 18651193 | — |
Reaction Steps
The above alcohol (0.21 g) was oxidised using the conditions of Swern (oxalyl chloride, 0.1 ml; dimethyl sulphoxide. 0.15 ml; triethylamine. 0.66 ml) to give (±)-[trans-2-(2,6-dichloro-4-pyridyl)cyclopropyl]methanal (0.2 g). NMR 1H: 9.44(1H,d), 6.96(2H,s),
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05202356 |
| Source dataset | uspto-grants-1993_04 |
| ORD ID | ord-d93bcde993984730bcfdcc795db737f7 |
| Source note | uspto-grants-1993_04 |