HCID 14495687, compound → HCID 19103786, compound

HRID 1590546Notes

Reaction equation

HRID 1590546 reaction equation
[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22]([O:24][C:25]3[CH:30]=[CH:29][C:28]([O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38]C)=[CH:27][CH:26]=3)=[O:23])=[CH:18][CH:17]=2)=[C:12]([F:40])[C:11]=1[F:41])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].C(OC1C=CC(C2C=CC(C(OC3C=CC(CCCCCCCC)=C(F)C=3)=O)=CC=2)=C(F)C=1F)CCCCCCC.C(OC1C=CC(C2C=CC(C(OC3C=CC(CCCCCCCC)=CC=3F)=O)=CC=2)=C(F)C=1F)CCCCCCC.C(OC1C=CC(C2C=CC(C(OC3C=CC(OCCCCCCCC)=CC=3F)=O)=CC=2)=C(F)C=1F)CCCCCCC.C(OC1C=CC(C2C=CC(C(O[C@H]3CC[C@H](CCCCC)CC3)=O)=CC=2)=C(F)C=1F)CCCCCCC.C(OC1C=CC(C2C=CC(C(OC3C=CC(CCCCCCC)=C(F)C=3)=O)=CC=2)=C(F)C=1F)CCCCCCC.C(OC1C=CC(C2C=CC(C(OC3C=CC(OCCCCCCCC)=C(F)C=3)=O)=CC=2)=C(F)C=1F)CCCCCCC>>[CH2:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([C:16]2[CH:21]=[CH:20][C:19]([C:22]([O:24][C:25]3[CH:30]=[CH:29][C:28]([O:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38])=[CH:27][CH:26]=3)=[O:23])=[CH:18][CH:17]=2)=[C:12]([F:40])[C:11]=1[F:41])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

8

Reactant 7

HCID 14495687HCID 14495687, compoundHCID 14495688HCID 14495688, compoundHCID 14495689HCID 14495689, compoundHCID 14495690HCID 14495690, compoundHCID 14495691HCID 14495691, compoundHCID 19767213HCID 19767213, compoundHCID 178443708HCID 178443708, compound

Product 1

HCID 19103786HCID 19103786, compound

Procedure

p-octyloxyphenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, C 83.8° SC 151.7° SA 154.9° N 165.4° I 4-octyl-3-fluorophenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, 4-octyl-2-fluorophenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, C 45.2°SC 84.3° N 120.7° I 4-octyloxy-2-fluorophenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, C 56.7° SC 103° N 141.6° I 4-heptyl-2-fluorophenyl heptyl-2,3-difluorophenyl-4'-yl-carboxylate, C<20° N 83.4° I trans-4-pentylcyclohexyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate C (67.8°Sc) 81.6° SA 97.5° N 132.4° I 4-heptyl-3-fluorophenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, C 44.7° SC (41°) SA 146° I 4-octyloxy-3-fluorophenyl 4-octyloxy-2,3-difluorobiphenyl-4'-ylcarboxylate, C 83.6° SC 116° SA 162.9° I.

Workup

  1. custom° SA 162.9° I

Sources & evidence

ORD record
ord-f54f857763a0408fbdb6e1efd9c96d85
Source dataset
uspto-grants-1993_04
Patent number
US05204019

Reaction notes

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