Allyl bromide → HCID 69979367, compound

Participants

Reaction Steps

To a solution of t-butylnitrite (0.24 ml, 2.1 mmol) and allylbromide (1.8 ml, 25.2 mmol) in 3 ml CH3CN 3-acetyl-5-nitroaniline (0.25 g, 1.4 mmol) was added, so that the temperature was maintained between 20 and 25° C., and the mixture was stirred for 10 min at room temperature. The volatile material in the reaction solution was then removed at reduced pressure to give 3-acetyl-5-nitroallylbenzene. 1H-NMR (CDCl3, 300 MHz) δ ppm: 8.61 (s, 1H), 8.25 (s, 1H), 8.10 (s, 1H), 6.03-5.88 (m, 1H), 5.23-5.11 (m, 2H), 3.55 (d, 2H).

Provenance & Evidence