Phenol → HCID 18505982, compound

HRID 1595087Notes

Reaction equation

HRID 1595087 reaction equation
[C:1]1([OH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:8][C:9]1([CH3:17])[CH2:14][CH:13]([CH3:15])[CH2:12][C:11](=O)[CH2:10]1>>[CH3:8][C:9]1([CH3:17])[CH2:14][CH:13]([CH3:15])[CH2:12][C:11]([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][C:1]=2[OH:7])([C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][C:1]=2[OH:7])[CH2:10]1

Participants

3

Reactant 2

HCID 996Phenol7×HCID 133983,3,5-Trimethylcyclohexanone5×

Product 1

HCID 18505982HCID 18505982, compound

Procedure

The amount of the phenol (A) added after the conversion of 3,3,5-trimethylcyclohexanone (B) has reached 90 mol % or over is preferably such that the total molar amount of the phenol (A) added (the total phenol (A) consisting of the phenol (A) introduced in carrying out the pre-reaction, the phenol (A) dropped in the form of a liquid mixture with 3,3,5-trimethylcyclohexanone (B) in the reaction mixture and the phenol (A) added after the conversion of 3,3,5-trimethylcyclohexanone (B) has reached 90 mol % or over) is 5 to 10 times, especially 6 to 8 times, based on the molar amount of 3,3,5-trimethylcyclohexanone (B). When the amount of the phenol (A) added after the conversion of 3,3,5-trimethylcyclohexanone (B) has reached 90 mol % or over falls within the above range, not only can the rise of the viscosity of the reaction mixture be suppressed to thereby ensure efficient operation but also the desired 3,3,5-trimethylcyclohexylidenebisphenol can be obtained at high yield. The degree of conversion (%) of 3,3,5-trimethylcyclohexanone (TMC) is defined by the formula:

Workup

  1. additionintroduced
  2. customthe pre-reaction

Sources & evidence

ORD record
ord-820684487be84032ad195bf57f859856
Source dataset
uspto-grants-2001_09
Patent number
US06284931B1

Reaction notes

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