4-Bromo-2,6-dimethylbenzaldehyde → 2,6-Dimethyl4-isopropylbenzyl alcohol

反応式

Br[C:2]1[CH:9]=[C:8]([CH3:10])[C:5]([CH2:6][OH:7])=[C:4]([CH3:11])[CH:3]=1.Br[C:13]1[CH:20]=C(C)C(C=O)=C(C)[CH:14]=1>>[CH3:10][C:8]1[CH:9]=[C:2]([CH:13]([CH3:20])[CH3:14])[CH:3]=[C:4]([CH3:11])[C:5]=1[CH2:6][OH:7]

参加物

反応物 2

HCID 110202224-Bromo-2,6-dimethylbenzaldehyde

HCID 14680145(4-Bromo-2,6-dimethylphenyl)methanol

生成物 1

HCID 154807012,6-Dimethyl4-isopropylbenzyl alcohol収率 95%

実験手順

4-Bromo-2,6-dimethylbenzyl alcohol, from 4-bromo-2,6-dimethylbenzaldehyde (Hjed, H. et al. Acta Chem. Scand. 1965, 19:2166); 95% yield, mp 117-119° C.

出典と根拠

ORDレコード: ord-01dc49bd606548d5a360a363b5466439
出典データセット: uspto-grants-2001_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06288101B1

反応ノート

読み込み中…