Water → n-Decylacrylamide Acrylamid

HRID 1596104Notes

Reaction equation

HRID 1596104 reaction equation
[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[CH2:6]([C:16](=[CH2:20])[C:17]([NH2:19])=[O:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].C(C1C=CC=CC=1C=C)=C.O>C(O)C>[C:1]([NH2:5])(=[O:4])[CH:2]=[CH2:3].[CH2:6]([C:16](=[CH2:20])[C:17]([NH2:19])=[O:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

Participants

6

Reactant 4

HCID 962WaterHCID 6579AcrylamideHCID 666661,2-DiethenylbenzeneHCID 212758792-Methylidenedodecanamide

Product 1

HCID 21275878n-Decylacrylamide Acrylamid

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Polystyrenesulfonate (22.5 mmoles, 3.918 g), acrylamide (3.45 mmoles, 0.245 g), n-decylacrylamide (3.45 mmoles, 0.729 g) and divinylbenzene (0.6 mmoles, 85.5 microL) were dissolved in 15 mL ethanol and 5 mL water in a 40 mL vial fitted with a septa cap. The solution was degassed by bubbling nitrogen through and 1 mole % AIBN was added as a solution. The polymerization solution was further degassed and the placed in a heated reaction block at 60° C. for 18 h. A creamy yellow gel formed.

Workup

  1. customThe solution was degassed
  2. customby bubbling nitrogen through and 1 mole % AIBN
  3. additionwas added as a solution
  4. customThe polymerization solution was further degassed
  5. customthe placed in a heated reaction block at 60° C. for 18 h
  6. customA creamy yellow gel formed

Sources & evidence

ORD record
ord-1837cbd58426404a81e9dc27d59f63e4
Source dataset
uspto-grants-2001_09
Patent number
US06290946B1

Reaction notes

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