Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3,7-Dibenzyl-3,7-diazabicyclo[3.3.1]nonane → 3-Benzyl-3,7-diazabicyclo[3.3.1]nonane
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3,7-Dibenzyl-3,7-diazabicyclo[3.3.1]nonane | HCID 47341 | — |
| 용매 | Ethanol | HCID 702 | — |
| 용매 | Palladium | HCID 23938 | — |
| 생성물 | 3-Benzyl-3,7-diazabicyclo[3.3.1]nonane | HCID 13059482 | — |
반응 단계
3,7-Dibenzyl-3,7-diazabicyclo[3.3.1]nonane (1.97 g; 6.4 mmol; from step (a) above) was dissolved in EtOH (95%) and hydrogenated over 5% Pd/C at 1 atm. until tlc indicated that the reaction was complete. The catalyst was removed by filtration through a pad of celite and the residue was concentrated under reduced pressure to give the title compound in a quantitative yield.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06291475B1 |
| 출처 데이터셋 | uspto-grants-2001_09 |
| ORD ID | ord-8850405cfb6b47c9aa35a303e49512b9 |
| 출처 메모 | uspto-grants-2001_09 |