HuagongsheHuagongshe Chemistry Print Report · For research reference only
Toluene → HCID 18931894, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Toluene | HCID 1140 | — |
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Phosphorus oxychloride | HCID 24813 | — |
| Reactant | 9-Phenylcarbazole | HCID 70851 | — |
| Catalyst | Zincchloride | HCID 3007855 | — |
| Product | HCID 18931894 | HCID 18931894 | 42.2% |
Reaction Steps
23.0 g (93.1 mmol) of 9-phenylcarbazole (4c) (manufactured by Aldrich Co.), 49.0 g (670.5 mmol) of DMF, 25.4 g (186.2 mmol) of zinc chloride, 85.7 g (558.7 mmol) of phosphorus oxychloride and 230 ml of toluene were allowed to react and after treated in the same manner as with Example 1 (1) to obtain 11.8 g of 3,6-diformyl-9-phenylcarbazole (2c).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05736284 |
| Source dataset | uspto-grants-1998_04 |
| ORD ID | ord-edea96aa67ee43edac4e70f23ccf72f0 |
| Source note | uspto-grants-1998_04 |