HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → 9-(Butan-2-yl)-9H-carbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | 2-Iodobutane | HCID 10559 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Catalyst | Tetrabutylammonium hydrogen sulfate | HCID 94433 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | 9-(Butan-2-yl)-9H-carbazole | HCID 20552621 | 24.1% |
Reaction Steps
30 g (179.46 mmol) of carbazole, 71 g of 85% KOH, 40 g of potassium carbonate, 6.0 g of tetra-n-butylammonium hydrogensulfate, 50.0 g (271.7 mmol) of 2-iodobutane and 300 ml of DMF were allowed to react and after treated in the same manner as with Example 7 (1) to obtain 9.66 g of 9-s-butylcarbazole.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05736284 |
| Source dataset | uspto-grants-1998_04 |
| ORD ID | ord-4f59987bfe024d109d20984462e93033 |
| Source note | uspto-grants-1998_04 |