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2-Chloro-4-methoxyphenol → Methyl 3,5-dinitro-4-(2'-chloro-4'-methoxyphenoxy)benzoate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Chloro-4-methoxyphenol | HCID 87459 | — |
| 反応物 | Methyl 4-chloro-3,5-dinitrobenzoate | HCID 96161 | — |
| 反応物 | Potassium 2-chloro-4-methoxyphenolate | HCID 23716091 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Methyl 3,5-dinitro-4-(2'-chloro-4'-methoxyphenoxy)benzoate | HCID 18349326 | 66% |
反応手順
The dinitro precursor was prepared by reacting 2-chloro-4-methoxyphenol (Aldrich Chemical Co., Milwaukee, Wis.) as the potassium 2-chloro-4-methoxyphenolate with methyl 4-chloro-3,5-dinitrobenzoate, as described in Example 1.2.1. The methyl 3,5-dinitro-4-(2'-chloro-4'-methoxyphenoxy)benzoate product (66% yield) was crystallized from ethanol to give orange crystals. Melting point: 116°-119° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05736576 |
| 出典データセット | uspto-grants-1998_04 |
| ORD ID | ord-b7823c37ff8c444d9373864ca58fd723 |
| 出典メモ | uspto-grants-1998_04 |