Toluene → HCID 18931649, compound

HRID 1599346Notes

Reaction equation

HRID 1599346 reaction equation
C1(C)C=CC=CC=1.[C:8]([C:12]1[CH:13]=[C:14]([CH2:23][CH2:24][C:25]([O:27][CH3:28])=[O:26])[CH:15]=[C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])[C:17]=1[OH:18])([CH3:11])([CH3:10])[CH3:9].C[O-].[Na+].[CH3:32][O:33][CH2:34]CO>>[C:8]([C:12]1[CH:13]=[C:14]([CH2:23][CH2:24][C:25]([O:27][CH2:28][CH2:32][O:33][CH3:34])=[O:26])[CH:15]=[C:16]([C:19]([CH3:20])([CH3:21])[CH3:22])[C:17]=1[OH:18])([CH3:9])([CH3:10])[CH3:11]

Participants

5

Reactant 4

HCID 1140TolueneHCID 80192-MethoxyethanolHCID 62603Methyl di-t-butyl hydroxyhydrocinnamateHCID 10942334Sodium Methoxide

Product 1

HCID 18931649HCID 18931649, compound

Procedure

The title compound was prepared from 90 g of toluene, 102.4 g of methyl 3-(3,5-di-t-butyl-4-hydroxyphenyl)-propionate, 18.2 g of ethylene glycol monomethyl ether and 0.35 g of sodium methoxide, by a procedure analogous to that of Example 10. Yield 42.2 g. Melting point 62°-64° C.

Sources & evidence

ORD record
ord-e80128106f7149369e95f685ec4e3df0
Source dataset
uspto-grants-1998_04
Patent number
US05739377

Reaction notes

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