1,3-Benzenedimethanamine → 3-Methylbenzylamine

HRID 1599777Notes

Reaction equation

HRID 1599777 reaction equation
[NH2:1][CH2:2][CH:3]1[CH2:8][CH2:7][CH2:6][CH:5]([CH2:9]N)[CH2:4]1.[C:11]1([CH2:19]N)[CH:16]=[CH:15][CH:14]=[C:13]([CH2:17][NH2:18])[CH:12]=1>C1(C)C=CC=C(C)C=1>[NH2:1][CH2:2][CH:3]1[CH2:8][CH2:7][CH2:6][CH:5]([CH3:9])[CH2:4]1.[CH3:19][C:11]1[CH:12]=[C:13]([CH:14]=[CH:15][CH:16]=1)[CH2:17][NH2:18]

Participants

5

Reactant 2

HCID 151331,3-BenzenedimethanamineHCID 174061,3-Bis(aminomethyl)cyclohexane

Product 2

HCID 660153-MethylbenzylamineHCID 18361468(3-Methylcyclohexyl)methanamine

Reagents, catalysts & solvents 1

HCID 7929M-XyleneSolvent

Procedure

As a result of analysis by gaschromatography, it was found the yield of 1,3-bis(aminomethyl)cyclohexane was 33.3 mol % and as other products 0.3 mol % of metaxylene, 0.6 mol % of 3-aminomethyl-1-methylcyclohexane, 4.7 mol of 3-methylbenzylamine and 61.1 mol % of unreacted metaxylylenediamine were obtained.

Workup

  1. customAs a result of analysis by gaschromatography, it

Sources & evidence

ORD record
ord-a4f7a89f905a452fb002fdf4b663c9e3
Source dataset
uspto-grants-1998_04
Patent number
US05741928

Reaction notes

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