HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1600444Generated: November 3, 2026
Azidotrimethylsilane → HCID 178420773, compound
https://huagongshe.com/reaction/1600444
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Azidotrimethylsilane | HCID 78378 | — |
| Reactant | 3-Ethynylpyridine | HCID 186003 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 178420773 | HCID 178420773 | — |
Reaction Steps
In a glass-coated bomb tube 6.5 g (0.063 mol) of 3-pyridyl acetylene (T. Sakamoto et al., Synthesis (1983) 312) and 8.7 g (0.075 mol) of trimethylsilyl azide were mixed and heated to 150° C. for 20 h. After cooling the mixture was poured into water. A colorless solid, 68, formed, which was isolated by filtration and dried. Yield: 4.0 g (0.028 mol, 44%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | USRE036374 |
|---|
| Source dataset | uspto-grants-1999_11 |
|---|
| ORD ID | ord-36347459bf8a48cbbc86fe5a55159288 |
|---|
| Source note | uspto-grants-1999_11 |
|---|
