4-Vinylphenol → p-1-Ethoxyethoxystyrene p-hydroxystyrene p-tert-butoxystyrene

HRID 1600508Notes

Reaction equation

[OH:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[CH2:7])=[CH:4][CH:3]=1.[C:10]([O:14][C:15]1[CH:22]=[CH:21][C:18]([CH:19]=[CH2:20])=[CH:17][CH:16]=1)([CH3:13])([CH3:12])[CH3:11]>>[CH2:10]([O:14][CH2:15][CH2:16][O:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[CH2:7])=[CH:4][CH:3]=1)[CH3:11].[OH:14][C:15]1[CH:22]=[CH:21][C:18]([CH:19]=[CH2:20])=[CH:17][CH:16]=1.[C:10]([O:1][C:2]1[CH:9]=[CH:8][C:5]([CH:6]=[CH2:7])=[CH:4][CH:3]=1)([CH3:13])([CH3:12])[CH3:11]

Participants

Reactant 2

HCID 624534-Vinylphenol

HCID 5775311-(Tert-butoxy)-4-ethenylbenzene

Product 1

HCID 131721427p-1-Ethoxyethoxystyrene p-hydroxystyrene p-tert-butoxystyrene

Procedure

Using 26.8 g of poly(p-hydroxystyrene/p-tert-butoxystyrene) obtained according to (2) above and 1.5 g of ethylvinyl ether, reaction and after-treatments were carried out according to (3) of Preparation Example 1 to obtain 25.0 g of poly(p-1-ethoxystyrene/p-hydroxystyrene/p-tert-butoxystyrene) as white powdery crystal. P-1-ethoxyethoxystyrene unit/p-hydroxystyrene unit/p-tert-butoxystyrene unit molar ratio in the polymer≈10:65:25. Mw≈1 9,200; Mw/Mn=1.30 (GPC with polystyrene calibration).

Sources & evidence

ORD record: ord-fedd762d737b47a2ba7f1b55b104273d
Source dataset: uspto-grants-1999_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05976759

Reaction notes

Loading…