Diisobutylaluminumhydride → HCID 18363299, compound

HRID 1601370Notes

Reaction equation

HRID 1601370 reaction equation
[F:1][C:2]([F:21])([F:20])[C:3]1[CH:8]=[CH:7][C:6](/[CH:9]=[CH:10]/[CH:11]=[CH:12]/[CH:13]=[CH:14]/[C:15](OCC)=[O:16])=[CH:5][CH:4]=1.[H-].C([Al+]CC(C)C)C(C)C>>[F:1][C:2]([F:20])([F:21])[C:3]1[CH:4]=[CH:5][C:6](/[CH:9]=[CH:10]/[CH:11]=[CH:12]/[CH:13]=[CH:14]/[CH2:15][OH:16])=[CH:7][CH:8]=1

Participants

3

Reactant 2

HCID 21225700DiisobutylaluminumhydrideHCID 86583808HCID 86583808, compound

Product 1

HCID 18363299HCID 18363299, compoundYield 90%

Procedure

Ethyl (2E,4E,6E)-7-[4-(trifluoromethyl)phenyl]-2,4,6-heptatrienoate was treated with diisobutyl aluminum hydride in the same manner as in Reference example 21 to obtain the title compound in a yield of 90%.

Sources & evidence

ORD record
ord-908825c498df4cb4abc8222ace4e7693
Source dataset
uspto-grants-1999_11
Patent number
US05977152

Reaction notes

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