HCID 18363299, compound → HCID 18363285, compound

HRID 1601371Notes

Reaction equation

HRID 1601371 reaction equation
[F:1][C:2]([F:18])([F:17])[C:3]1[CH:8]=[CH:7][C:6](/[CH:9]=[CH:10]/[CH:11]=[CH:12]/[CH:13]=[CH:14]/[CH2:15][OH:16])=[CH:5][CH:4]=1>[O-2].[O-2].[Mn+4]>[F:1][C:2]([F:17])([F:18])[C:3]1[CH:4]=[CH:5][C:6](/[CH:9]=[CH:10]/[CH:11]=[CH:12]/[CH:13]=[CH:14]/[CH:15]=[O:16])=[CH:7][CH:8]=1

Participants

3

Reactant 1

HCID 18363299HCID 18363299, compound

Product 1

HCID 18363285HCID 18363285, compoundYield 88%

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

(2E,4E,6E)-7-[4-(Trifluoromethyl)phenyl]-2,4,6-heptatrien-1-ol was treated with active manganese dioxide in the same manner as in Reference example 22 to obtain the title compound in a yield of 88%.

Sources & evidence

ORD record
ord-33d645dab41a4150a78be4311ef6f753
Source dataset
uspto-grants-1999_11
Patent number
US05977152

Reaction notes

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