HCID 86583788, compound → HCID 10589408, compound

HRID 1601374Notes

Reaction equation

HRID 1601374 reaction equation
C([CH:3]([OH:22])/[CH:4]=[CH:5]/[CH:6]=[CH:7]/[C:8]1[CH:13]=[CH:12][C:11]([O:14][CH2:15][C:16]([F:21])([F:20])[CH:17]([F:19])[F:18])=[CH:10][CH:9]=1)C>[O-2].[O-2].[Mn+4]>[F:20][C:16]([F:21])([CH:17]([F:18])[F:19])[CH2:15][O:14][C:11]1[CH:10]=[CH:9][C:8](/[CH:7]=[CH:6]/[CH:5]=[CH:4]/[CH:3]=[O:22])=[CH:13][CH:12]=1

Participants

3

Reactant 1

HCID 86583788HCID 86583788, compound

Product 1

HCID 10589408HCID 10589408, compoundYield 96%

Reagents, catalysts & solvents 1

HCID 178418406HCID 178418406, compoundCatalyst

Procedure

Ethyl (2E,4E)-5-[4-(2,2,3,3-tetrafluoropropoxy)phenyl]-2,4-pentadien-1-ol was treated with active manganese dioxide in the same manner as in Reference example 22 to obtain the title compound having a melting point of 53 to 55° C. in a yield of 96%.

Sources & evidence

ORD record
ord-40901e43daf940bba850fad1fb55d879
Source dataset
uspto-grants-1999_11
Patent number
US05977152

Reaction notes

Loading…