2-Tetralone → HCID 54148041, compound

HRID 1602196Notes

Reaction equation

[CH2:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][C:2]1=[O:11].[N+:12]([C:15]1[CH:22]=[C:21]([O:23][CH3:24])[C:20]([O:25][CH3:26])=[CH:19][C:16]=1[CH:17]=O)([O-:14])=[O:13]>>[N+:12]([C:15]1[CH:22]=[C:21]([O:23][CH3:24])[C:20]([O:25][CH3:26])=[CH:19][C:16]=1[CH:17]=[C:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH2:4][CH2:3][C:2]1=[O:11])([O-:14])=[O:13]

Participants

Reactant 2

HCID 682662-Tetralone

HCID 885056-Nitroveratraldehyde

Product 1

HCID 54148041HCID 54148041, compound

Procedure

Prepared from 2-tetralone and 2-nitro-4,5-dimethoxybenzaldehyde; mp 58-60° C.; IR (Nujol): 1724, 1540; 1H NMR: δ2.71 (2H, t), 3.08 (2H t), 3.56 (3H, s), 4.02 (3H, s), 6.51 (1H, s), 6.92-6.96 (2H, m), 7.17-7.24 (2H, m), 7.73 (1H, s), 8.00 (1H, s); 13C NMR: δ28.3, 27.8, 56.7, 56.9, 108.3, 112.5, 126.7, 127.6, 128.5, 128.8, 129.9, 132.3, 133.4, 134.5, 138.8, 141.6, 149.4, 153.5.

Sources & evidence

ORD record: ord-6c6f373275dc4d1da18896964bcca3b1
Source dataset: uspto-grants-1999_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05981541

Reaction notes

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